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81.
Yakupova Z. R. Lebedinets S. A. Vakh K. S. Garmonov S. Yu. Bulatov A. V. 《Journal of Analytical Chemistry》2022,77(3):342-346
Journal of Analytical Chemistry - A method is proposed for the chromatographic determination of 17-β-estradiol in medicinal preparations with the microextraction of the analyte from a sample... 相似文献
82.
Ultrasound has been recognized as an exciting tool to enhance the therapeutic efficacy in tumor chemotherapy owing to the triggered drug release, facilitated intracellular drug delivery, and improved spatial precision. Aiming for a precise localized drug delivery, novel dendritic polyurethane-based prodrug (DOX-DPU-PEG) was fabricated with a drug content of 18.9% here by conjugating DOX onto the end groups of the functionalized dendritic polyurethane via acid-labile imine bonds. It could easily form unimolecular micelles around 38 nm. Compared with the non-covalently drug-loaded unimolecular micelles (DOX@Ph-DPU-PEG), they showed excellent pH/ultrasound dual-triggered drug release performance, with drug leakage of only 4% at pH 7.4, but cumulative release of 14% and 88% at pH 5.0 without and with ultrasound, respectively. The ultrasound responsiveness was attributed to the unique strawberry-shaped topological structure of the DOX-DPU-PEG, in which DOX was embedded in the skin layer of the hydrophobic DPU cores. With ultrasound, the DOX-DPU-PEG unimolecular micelles possessed enhanced tumor growth inhibition than free DOX but showed no obvious cytotoxicity on the tumor cells without ultrasound. Such feature makes them promising potential for precise localized drug delivery. 相似文献
83.
Dev Raj Alok Kumar Rohit Kumar Singh Abhishek Singh Bhadouria A.S.K. Sinha Deepak Dwivedi 《Current Opinion in Electrochemistry》2022
As the application of electrocatalyst continues to expand, envisaging the hidden mechanisms occurring at various length scale affecting the catalytic efficiency became important. To enhance the stability of electrocatalyst and reduce the cost, it is of paramount importance to reveal the active site's dynamics (using in situ techniques for getting the real-time information) which directly affect the reactions such as oxygen evolution reaction, hydrogen evolution reaction, and so on. Since such reactions are crucial for many engineering and scientific applications, in situ characterization techniques are required, which could capture such reactions happening at a different length and time scale. This article analyzes the recent progress made in the field of electrocatalyst's characterization using in situ neutron techniques. The article also paves the future path and has delineated the future challenges involved in multiscale correlative techniques (e.g., neutron techniques in the combination of synchrotron or microscopic techniques) used for getting the multiscale (atomic to micrometer range) mechanistic information about the electrocatalyst's working and degradation. 相似文献
84.
Russian Physics Journal - The paper deals with the low-temperature physical mechanism of inelastic strain of metallic glass, which is the quantum atomic tunneling in a double well potential or... 相似文献
85.
Journal of Russian Laser Research - We construct Gaussian coherent states of a free particle with time-dependent mass, using symplectic tomographic probability distribution and integrals of motion... 相似文献
86.
Chumaevskii A. V. Zykova A. P. Gusarova A. V. Guryanov D. A. Rubtsov V. E. Kolubaev E. A. 《Russian Physics Journal》2022,65(2):303-311
Russian Physics Journal - The results of model experimental studies of structural-phase changes in an AA2024 aluminum alloy after friction with a counter-body of a complex configuration are... 相似文献
87.
88.
Stoyanovskii O. I. Galutskii V. G. Kotov D. I. 《Journal of Applied Mechanics and Technical Physics》2022,63(2):321-328
Journal of Applied Mechanics and Technical Physics - The wear resistance of DI37-VI and EK80-VI steel is studied using a friction testing device. A sample made of high-carbon chromium-vanadium... 相似文献
89.
Given a graph sequence denote by T3(Gn) the number of monochromatic triangles in a uniformly random coloring of the vertices of Gn with colors. In this paper we prove a central limit theorem (CLT) for T3(Gn) with explicit error rates, using a quantitative version of the martingale CLT. We then relate this error term to the well-known fourth-moment phenomenon, which, interestingly, holds only when the number of colors satisfies . We also show that the convergence of the fourth moment is necessary to obtain a Gaussian limit for any , which, together with the above result, implies that the fourth-moment condition characterizes the limiting normal distribution of T3(Gn), whenever . Finally, to illustrate the promise of our approach, we include an alternative proof of the CLT for the number of monochromatic edges, which provides quantitative rates for the results obtained in [7]. 相似文献
90.
Mathematical Notes - A system of new differential-geometric notions as the result of an analysis of the Trudinger–Wang inequalities is proposed. Their naturalness in multivariate analysis and... 相似文献